synthesis and cyclic voltammetric studies of bis[5-((4-alkoxyphenyl)azo)-n-(npentyl, ndodecyl)-salicylaldiminato] copper(ii) complex homologues

نویسندگان

ali akbar khandar

z. rezvani

چکیده

5-((4-alkoxyphenyl)azo)salicyladehyde, 5-((4-alkoxyphenyl)azo)-n-(npentyl, ndodecyl)-salicyladimine and bis [5-((4-alkoxyphenyl)azo)-n-(npentyl, ndodecyl)-salicyladiminato]copper(ii) [alkoxy=oncnh2n+1; n=3-7] homologues were synthesized and characterized by elemental analyses, mass and ir spectra. all complex homologues are thermally stable. cyclic voltammetric studies indicated that all copper complex homologues have a quasi-reversible redox wave and peak current ratio (ipa/ipc)decreasing with increase of alkyl chain length.

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Synthesis and Cyclic Voltammetric Studies of Bis[5-((4-Alkoxyphenyl)Azo)-N-(nPentyl, nDodecyl)-Salicylaldiminato] Copper(II) Complex Homologues

5-((4-alkoxyphenyl)azo)salicyladehyde, 5-((4-alkoxyphenyl)azo)-N-(npentyl, ndodecyl)-salicyladimine and bis [5-((4-alkoxyphenyl)azo)-N-(npentyl, ndodecyl)-salicyladiminato]copper(II) [alkoxy=OnCnH2n+1; n=3-7] homologues were synthesized and characterized by elemental analyses, mass and IR spectra. All complex homol...

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عنوان ژورنال:
iranian journal of chemistry and chemical engineering (ijcce)

ناشر: iranian institute of research and development in chemical industries (irdci)-acecr

ISSN 1021-9986

دوره 18

شماره 1 1999

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